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Understanding the Effects of Engineered Nanomaterials on Mammalian Cells and Plants Using a Mass Spectrometry Based Approaches
(State University of New York at Buffalo, 2019)
Nanotechnology focuses on the development and application of materials in the nanoscale range. Engineered nanomaterials (ENMs) are usually defined as particles of 1-100 nm in size in at least one dimension, which have been ...
Chalcogenopyrylium Dyes for Multiplex Biosensing
(State University of New York at Buffalo, 2019)
Surface enhanced Raman scattering (SERS) has gained recognition as a biomedical imaging technique because of its sensitivity and multiplexing capabilities. By sensing multiple disease biomarkers at once, early disease ...
Phosphorescent Chromophores as Structural Tectons for Coordination-Driven Self-Assembly Leading to Emergent Photophysical Properties.
(State University of New York at Buffalo, 2019)
Coordination-driven self-assembly is a synthetic methodology that allows for the creation of metallacycles and metallacages from component Lewis-acid acceptors and Lewis-basic donors as building blocks, or tectons. By using ...
Exploring the versatile role of doubly resonant sum frequency spectroscopy in molecular characterization of self-assembled and solid interfaces
(State University of New York at Buffalo, 2019)
Vibrational sum frequency generation (VSFG) spectroscopy is a nonlinear linear optical technique used, in general, to study the resonant infrared frequencies of chemical systems which lack centrosymmetry at the molecular ...
MECHANISTIC INSIGHTS INTO THE CATALYTIC MECHANISM AND INHIBITION OF MYCOBACTERIUM TUBERCULOSIS ISOCITRATE LYASE
(State University of New York at Buffalo, 2019)
Mycobacterium tuberculosis, the causative organism for tuberculosis, is responsible for the highest mortality rate among bacterial pathogens. Persistent M. tuberculosis infections depend on the glyoxylate shunt, a ...
A Lipidomics-Based Approach to Study Fatostatin-Induced Toxicity
(State University of New York at Buffalo, 2019)
Despite the well-known biological heterogeneity that exists between different types of cancer, they each undergo metabolic reprogramming to promote unregulated proliferation and tumor growth. This metabolic reprogramming ...
Determining Conformational Preferences of Shape-Persistent Aromatic Oligoamides and Folding of Aromatic Oligoureas with Ion-Pair Associations
(State University of New York at Buffalo, 2019)
The synthesis and characterization of folding aromatic oligoamides with reducedconstraint, ion-pair associations and solvent-mediated folding of aromatic oligoureas, andoligoamides with unique conformational variations ...
Boron, Boron Hyperdoped Silicon and Silicon Nanoparticle Synthesis by Laser Pyrolysis with Applications in Energy Storage
(State University of New York at Buffalo, 2018)
This dissertation presents three examples of how laser pyrolysis synthesis can be used to develop new nanomaterials for energy applications. In the first chapter, we will discuss synthesis, characterization and application ...
Interactions at the Surface-Adsorbate Interface: An Outlook Through Computational Work
(State University of New York at Buffalo, 2018)
The interaction between surfaces and adsorbates are discussed from the results of a multitude of different projects. Single molecule adsorption, molecular cluster formation, and hydrogen bonded molecular networks were ...
Aerobic Photoredox Reactions with Chalcogenorosamine Photosensitizers
(State University of New York at Buffalo, 2018)
Photocatalysis is a single-electron-transfer (SET) process that employs organic dyes or transition metal complexes along with visible light irradiation.1 Organic dyes have been utilized to a limited extent in photoredox ...