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Phosphorescent Chromophores as Structural Tectons for Coordination-Driven Self-Assembly Leading to Emergent Photophysical Properties.
(State University of New York at Buffalo, 2019)
Coordination-driven self-assembly is a synthetic methodology that allows for the creation of metallacycles and metallacages from component Lewis-acid acceptors and Lewis-basic donors as building blocks, or tectons. By using ...
Coordination-Driven Self-Assembly of Cofacial Porphyrin Prisms as Oxygen Reduction Catalysts
(State University of New York at Buffalo, 2018)
This thesis encompasses a suite of coordination-driven self-assembled porphyrin prisms differing in the molecular clips linking two porphyrin faces in a cofacial arrangement. The goal of this work was to apply the facile ...